We report rate coefficients for the relaxation of OH(v = 1) by O2 and N2O as a function of temperature. The rate coefficients for relaxation (in units of 10−13 cm3 molecule−1 s−1) can be fit by the following expressions: The results are discussed in terms of the possible mechanisms for relaxation, especially the influence of the weak chemical interaction between OH radicals and O2.
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1. Rate coefficients for the relaxation of OH(v=1) by O2 at Temperatures from 204-371 K and by NO2 from 243-372 K..
David C. McCabe, B. Rajakumar, I. W. M. Smith, A. R. Ravishankara. Chem. Phys, 2006, 111-117, 421